Enantioselective reductive allylic alkylation enabled by dual photoredox/palladium catalysis. Issue 9 (11th January 2023)
- Record Type:
- Journal Article
- Title:
- Enantioselective reductive allylic alkylation enabled by dual photoredox/palladium catalysis. Issue 9 (11th January 2023)
- Main Title:
- Enantioselective reductive allylic alkylation enabled by dual photoredox/palladium catalysis
- Authors:
- Tang, Sheng
Zhang, Hong-Hao
Yu, Shouyun - Abstract:
- Abstract : A dual photoredox/palladium catalyzed regio- and enantioselective reductive cross-coupling of allylic acetates with alkyl bromides has been achieved. Abstract : A dual photoredox/palladium catalyzed regio- and enantioselective reductive cross-coupling of allylic acetates with tertiary/secondary alkyl bromides has been achieved, and Hantzsch ester is used as a homogeneous organic reductant. This straightforward protocol enables the stereoselective construction of C(sp 3 )–C(sp 3 ) bonds under mild reaction conditions. Mechanistic studies suggest that this reaction involves radical pathways and a chiral Pd complex enables the control of the regio- and enantioselectivities.
- Is Part Of:
- Chemical communications. Volume 59:Issue 9(2023)
- Journal:
- Chemical communications
- Issue:
- Volume 59:Issue 9(2023)
- Issue Display:
- Volume 59, Issue 9 (2023)
- Year:
- 2023
- Volume:
- 59
- Issue:
- 9
- Issue Sort Value:
- 2023-0059-0009-0000
- Page Start:
- 1153
- Page End:
- 1156
- Publication Date:
- 2023-01-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc06705f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 25513.xml