Green and Efficient Method for Recycling Valuable Metals from Scrapped Lithium Cobalt Oxide Cathode Materials. Issue 5 (April 2020)

• Record Type: Journal Article
• Authors: Guo, Miaomiao; Xi, Xiaoli; Zhang, Dongdong; Yang, Hang; Bi, Fan; Hu, Yi; Nie, Zuoren; Xu, Kaihua
• Is Part Of: IOP conference series. Volume 474:Issue 5(2020)
• Publication Date: 2020-04
• Subjects: Earth sciences -- Periodicals; Environmental sciences -- Congresses; Environmental sciences -- Periodicals; 550.5
• DOI: 10.1088/1755-1315/474/5/052014
• Languages: English
• ISSNs: 1755-1307

Abstract

Abstract: In this study, green and efficient method for recycling valuable metals from scrapped lithium cobalt oxide cathode materials to form lithium carbonate and cobalt powder was proposed. To this end, aluminum and iron impurities were efficiently removed from scrapped lithium cobalt oxide cathode materials through alkali dissolution and magnetic separation with removal rates of 99.9% and 98.3%, respectively. After removal of impurities, lithium cobalt oxides were reduced by hydrogen at high temperature of 650 °C for 3 h to yield Li2O, Co, and very small amounts of CoO and LiOH. Next, the mixture was subjected to water leaching and sodium carbonate precipitation to obtain lithium carbonate with purity of 99.5%. The water-leaching Co and small amounts of cobalt oxides were again reduced by hydrogen to form cobalt powder with purity of 99.4%. In sum, the proposed method looks promising in terms of efficiency, easy for implementation, environmentally-friendliness, and potential industrialization.