Transition metal–incorporated tungsten-based ternary refractory metal selenides (MWSex; M = Fe, Co, Ni, and Mn) as hydrogen evolution catalysts at soft interfaces. (December 2020)

• Record Type: Journal Article
• Authors: Aslan, E.; Sarilmaz, A.; Yanalak, G.; Ozel, S.S.; Ozel, F.; Patir, I.H.
• Is Part Of: Materials today energy. Volume 18(2020)
• Publication Date: 2020-12
• Subjects: Ternary metal selenides -- Hydrogen evolution reaction -- Liquid/liquid interfaces -- Iron tungsten selenide -- Manganese tungsten selenide; Energy development -- Periodicals; Energy industries -- Periodicals; Power resources -- Periodicals; Energy policy -- Periodicals; Energy development; Energy industries; Energy policy; Power resources; Electronic journals; Periodicals; 621.042
• DOI: 10.1016/j.mtener.2020.100510
• Languages: English
• ISSNs: 2468-6069

Abstract

Abstract: Hydrogen evolution reaction (HER) catalysts including transition metal chalcogenides have been recognized as a class of very promising non-expensive and earth-abundant catalysts. Tremendous investigations on the binary and ternary metal sulfides/selenides have demonstrated extraordinary chemical and physical properties such as good structural stability and adjustable chemical composition. The ternary amorphous refractory metal selenides (MWSex ; M = Fe, Co, Ni, Mn) have been synthesized by the hot-injection method. The NiWSex, CoWSex, FeWSex and MnWSex nanostructures have been used as catalysts for the hydrogen evolution at the biphasic systems of water and 1, 2-dichloroethane with similar to a biomembrane. The catalytic activity differences of ternary metal selenides have been compared with each other taking into account transition metals which are changed in the order of Fe ≈ Mn ≪ Co < Ni. The catalytic activities of the MWSex have not been changed when adding of Fe and Mn into the tungsten selenide nanostructure, which may be originated from amorphous structures of FeWSex and MnWSex . Ni and Co addition into the tungsten selenide have improved the electrocatalytic HER activity when compared with only WSex . Graphical abstract: Image 1 Highlights: MWSex electrocatalysts use in first systematic hydrogen evolution catalysis. Hydrogen evolution reaction (HER) by MWSex electrocatalysts investigates first-time by using biphasic reactions. The rates of HER change in the order of Ni > Co > Fe ≈ Mn.