Engineering a local potassium cation concentrated microenvironment toward the ampere-level current density hydrogen evolution reaction. Issue 1 (21st December 2022)

• Record Type: Journal Article
• Authors: Gao, Lei; Bao, Feixiang; Tan, Xin; Li, Mengfan; Shen, Zhen; Chen, Xuli; Tang, Ziyi; Lai, Wenchuan; Lu, Yangfan; Huang, Peifeng; Ma, Chao; Smith, Sean C.; Ye, Zhizhen; Hu, Zheng; Huang, Hongwen
• Is Part Of: Energy & environmental science. Volume 16:Issue 1(2023)
• Page Start: 285
• Page End: 294
• Publication Date: 2022-12-21
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/d2ee02836k
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Finding an active and robust non-platinum catalyst toward the alkaline hydrogen evolution reaction (HER) operating at an ampere-level current density is important for emerging anion exchange membrane (AEM) water electrolysis but challenging. Abstract : Finding an active and robust non-platinum catalyst toward the alkaline hydrogen evolution reaction (HER) operating at an ampere-level current density is important for emerging anion exchange membrane (AEM) water electrolysis but challenging. Here we report a nanocone-assembled Ru3 Ni (NA-Ru3 Ni) catalyst that exhibits a low overpotential of 168 mV at 1000 mA cm −2 and a high turnover frequency of 26.5 s −1 at an overpotential of 100 mV, with a Ru3 Ni loading of only 0.08 mg cm −2 . Moreover, the catalyst could stably operate at 1000 mA cm −2 over 2000 h in a practical AEM electrolyser at 60 °C, showing the best overall performance among ever-reported catalysts. The theoretical simulations and experimental results confirm that the sharp-tip concentrated K + cations contribute to such remarkable alkaline HER activity by intensifying the polarization of the H–OH bond of interfacial water and decreasing the energy barrier for water dissociation, where the non-covalent interaction is considered as the intrinsic driving force. The present work provides general guidance for the rational design of industrially relevant alkaline HER catalysts.