The Effect of Electrode Morphology on Solid Oxide Fuel Cell Performance. (2nd June 2015)

• Record Type: Journal Article
• Authors: Pharoah, Jon G.; Handl, Lisa; Schmidt, Volker
• Is Part Of: ECS transactions. Volume 68:Number 1(2015)
• Page Start: 2037
• Page End: 2045
• Publication Date: 2015-06-02
• Subjects: Electrochemistry -- Periodicals; Electrochemistry; Periodicals; Electronic journals; Electronic journal; 541.37
• DOI: 10.1149/06801.2037ecst
• Languages: English
• ISSNs: 1938-5862

Abstract

Abstract : Three different electrode morphologies are generated from three different starting powders, spheres representing non-aggregated powders, agglomerates of spheres and high aspect ratio cylinders modelling splats formed in plasma sprays. Electrodes from each morphology are analysed using finite volumes to predict the effective transport coefficients, the triple phase boundary length and the performance of the electrode. The same structures are also analysed using morphological characterization which can be much more efficient. It was found that high aspect ratio base particles are favourable, and that constrictivity correlates best with the finite volume transport calculations.