Fabrication and thermoelectric property of the nano Fe2O3/carbon fiber/cement-based composites for potential energy harvesting application. (15th February 2023)

• Record Type: Journal Article
• Authors: Wan, Ye; Tan, Shuo; Li, Lijun; Zhou, Honghong; Zhao, Lijia; Li, Hang; Han, Zhongxu
• Is Part Of: Construction & building materials. Volume 365(2023)
• Publication Date: 2023-02-15
• Subjects: Cement paste -- Dispersant -- Thermoelectric property -- Seebeck effect -- Figure of merit -- Mechanical property; Building materials -- Periodicals; 624.18
• DOI: 10.1016/j.conbuildmat.2022.130021
• Languages: English
• ISSNs: 0950-0618

Abstract

Graphical abstract: Illustration of fabrication process for the cement composite brick. Highlights: CFs, nano Fe2 O3 and dispersant were incorporated in the cement composites. The maximum Seebeck coefficient of the cement composite is 1.1234 mV ∙ K - 1 . The highest ZT is 8.51 × 10 −5 even with very low addition of CFs and Fe2 O3 at 85 °C. The composites have potential application in energy harvesting in infrastructures. Abstract: Cement based thermoelectric materials have attracted great interest due to their fascinating prospects for harvesting, storing and further converting the absorbed ambient energy into electrical energy. In this paper, nano Fe2 O3 /carbon fiber (CF)/cement-based composites were fabricated by introduced nano Fe2 O3, CFs and polyoxyethylene nonyl phenyl ether (TX10) into cement matrix. The thermoelectric and the mechanical properties, and the surface structures were investigated as well. The results show TX10 promoted dispersion for both of CF and nano Fe2 O3 particles in the cement. The nano Fe2 O3 /CF/cement-based composites incorporated with 0.6 (wt.) % TX10 revealed not only better thermoelectric effects, but also denser structure, higher mechanical strengths and smaller surface area than the composites with other adding levels of TX10. We report the maximum Seebeck coefficient of 1.1234 mV ∙ K - 1 and the highest thermoelectric figure of merit (ZT) of 8.51 × 10 −5 (85 °C) in this work. The enhanced thermoelectric properties of the nano Fe2 O3 /CF/cement-based composites are appealing for potential application in energy harvesting and storing, and thus alleviating the urban heat island (UHI) effect.