A new adsorption energy-barrier relation and its application to CO2 hydrogenation to methanol over In2O3-supported metal catalysts. Issue 7 (4th January 2023)

• Record Type: Journal Article
• Authors: Yang, Deshuai; Lu, Huili; Zeng, Guixiang; Chen, Zhao-Xu
• Is Part Of: Chemical communications. Volume 59:Issue 7(2023)
• Page Start: 940
• Page End: 943
• Publication Date: 2023-01-04
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc05571f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A new thermodynamics-kinetics relation called adsorbate-dependent barrier scaling (ADBS) relation is discovered and used to predict the catalytic activity of a series of In2 O3 -supported metal and alloy catalysts for CO2 hydrogenation to methanol. Abstract : Herein, we report a new adsorption energy-barrier relation, the adsorbate-dependent barrier scaling (ADBS) relation, with which the catalytic activity of In2 O3 -supported metal catalysts for CO2 hydrogenation to methanol is predicted. It is shown that Cu, Ga, NiPt and NiPd alloys exhibit high catalytic activity for CO2 hydrogenation to methanol.