On the limits of observing motion in time-resolved X-ray scattering. (20th May 2019)

• Record Type: Journal Article
• Authors: Ware, Matthew R.; Glownia, James M.; Natan, Adi; Cryan, James P.; Bucksbaum, Philip H.
• Is Part Of: Philosophical transactions. Volume 377:Number 2145(2019)
• Publication Date: 2019-05-20
• Subjects: time-resolved X-ray scattering -- molecular movies -- X-ray free electron lasers; Physical sciences -- Periodicals; Engineering -- Periodicals; Mathematics -- Periodicals; 500
• DOI: 10.1098/rsta.2017.0477
• Languages: English
• ISSNs: 1364-503X

Abstract

Abstract : Limits on the ability of time-resolved X-ray scattering (TRXS) to observe harmonic motion of amplitude, A and frequency, ω 0, about an equilibrium position, R 0, are considered. Experimental results from a TRXS experiment at the LINAC Coherent Light Source are compared to classical and quantum theories that demonstrate a fundamental limitation on the ability to observe the amplitude of motion. These comparisons demonstrate dual limits on the spatial resolution through Q max and the temporal resolution through ω max for observing the amplitude of motion. In the limit where ω max ≈ ω 0, the smallest observable amplitude of motion is A = 2 π / Q max . In the limit where ω max ≥2 ω 0, A ≤2 π / Q max is observable provided there are sufficient statistics. This article is part of the theme issue 'Measurement of ultrafast electronic and structural dynamics with X-rays'.