A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones. Issue 5 (23rd May 2018)
- Record Type:
- Journal Article
- Title:
- A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones. Issue 5 (23rd May 2018)
- Main Title:
- A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones
- Authors:
- Cortés, Iván
Kaufman, Teodoro S.
Bracca, Andrea B. J. - Abstract:
- Abstract : The use of CeCl3 ·7H2 O as an efficient and eco-friendly promoter for the convenient synthesis of methoximes derived from aromatic aldehydes and ketones, is reported. The transformations entail the use of equimolar amounts of MeONH2 ·HCl and NaOAc in EtOH at 50°C, and no special precautions are needed with regard to the presence of oxygen. The scope and limitations of the transformation were studied and a reaction mechanism was proposed.
- Is Part Of:
- Royal Society open science. Volume 5:Issue 5(2018)
- Journal:
- Royal Society open science
- Issue:
- Volume 5:Issue 5(2018)
- Issue Display:
- Volume 5, Issue 5 (2018)
- Year:
- 2018
- Volume:
- 5
- Issue:
- 5
- Issue Sort Value:
- 2018-0005-0005-0000
- Page Start:
- Page End:
- Publication Date:
- 2018-05-23
- Subjects:
- cerium(III) chloride-promoted reaction -- methoximation -- eco-friendly transformation
Science -- Periodicals
500 - Journal URLs:
- https://royalsocietypublishing.org/journal/rsos ↗
- DOI:
- 10.1098/rsos.180279 ↗
- Languages:
- English
- ISSNs:
- 2054-5703
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library STI - ELD Digital store
- Ingest File:
- 25063.xml