A magnetically retrievable air and moisture stable gold and palladium nanocatalyst for efficient C−C coupling reactions. Issue 9 (30th September 2020)

• Record Type: Journal Article
• Authors: Goonesinghe, Chatura; Shaik, Mohamed; Ratnaweera, Rivi; Nalin De Silva, K. M.; De Silva, Rohini M.
• Is Part Of: Royal Society open science. Volume 7:Issue 9(2020)
• Publication Date: 2020-09-30
• Subjects: palladium -- magnetic -- C–C coupling -- heterogeneous -- recyclable catalysts; Science -- Periodicals; 500
• DOI: 10.1098/rsos.200916
• Languages: English
• ISSNs: 2054-5703

Abstract

Abstract : In this study, we report the synthesis of a highly stable, magnetically retrievable gold and palladium nanocatalyst (AuPd@AMNPs), highly active in Suzuki cross-coupling and related homocoupling reactions. The active catalytic component in this system is palladium, which can only be stabilized in the presence of gold nanoparticles. There is no significant loss of activity even after prolonged storage exposed air and moisture. The versatile nature AuPd@AMNPs is demonstrated through the selective catalysis of the homocoupling of phenylboronic acid under low concentrations of O2 and the oxidation of phenylboronic acid to phenol under high O2 concentrations. AuPd@AMNPs also demonstrated Ullmann-type homocoupling of 4-iodotolene with excellent yields. The magnetically retrieved catalyst could be re-used up to six times in Suzuki–Miyaura cross-coupling with consistently high activity and with a minimal loss of the noble metal species. Through these reactions we show that the gold-stabilized AuPd@AMNPs can be used as stable and recyclable palladium reservoir for multiple palladium-catalysed reactions.