Cost‐Effective H2O2‐Regeneration of Powdered Activated Carbon by Isolated Fe Sites. Issue 2 (18th November 2022)

• Record Type: Journal Article
• Authors: Chen, Xu; Tian, Ziqi; Yang, Qihao; Zhang, Linjuan; Yang, Qiu; Chen, Liang; Lu, Zhiyi
• Is Part Of: Advanced science. Volume 10:Issue 2(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-18
• Subjects: Fe‐based reactive oxygen species (ROS) -- nonradical Fenton‐like -- powdered activated carbon -- regeneration; Science -- Periodicals; 505
• DOI: 10.1002/advs.202204079
• Languages: English
• ISSNs: 2198-3844

Abstract

Abstract: The reuse of powdered activated carbon (PAC) vitally determines the economics and security of the PAC‐based adsorption process, while state‐of‐the‐art PAC regeneration technologies are usually unsatisfactory. Here, it is demonstrated that isolated Fe sites anchored on commercial PAC enable fast H2 O2 activation to produce Fe‐based reactive oxygen species for highly efficient PAC regeneration at room temperature. Taking rhodamine B as a representative pollutant, PAC decorated with isolated Fe sites realize H2 O2 based regeneration with negligible adsorption capacity degradation for 10 cycles. Moreover, in terms of the PAC loss rate, this technology is greatly superior to traditional Fenton‐based regeneration technology. Further operando experiments and theoretical calculations reveal that the high regeneration performance can be attributed to the isolated HOFeO motifs, which activate H2 O2 via a nonradical reaction pathway. These findings provide a very promising strategy toward reducing the cost of H2 O2 ‐based PAC regeneration technology. Abstract : Commercial powdered activated carbon decorated with isolated Fe‐O5 sites enables fast H2 O2 activation and realizes H2 O2 ‐based regeneration with negligible adsorption capacity degradation for ten cycles. Further operando experiments and theoretical calculations reveal that the high regeneration performance is attributed to the isolated HOFeO motifs, which activate H2 O2 via a nonradical reaction pathway to produce Fe‐base ROS.