Upconversion Luminescence through Cooperative and Energy‐Transfer Mechanisms in Yb3+‐Metal‐Organic Frameworks. (19th December 2022)

• Record Type: Journal Article
• Authors: Xie, Yao; Sun, Guotao; Mandl, Gabrielle A.; Maurizio, Steven L.; Chen, Jiabo; Capobianco, John A.; Sun, Lining
• Is Part Of: Angewandte Chemie. Volume 135:Number 4(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-12-19
• Subjects: Cooperative Luminescence -- Energy Transfer -- Lanthanides -- Metal–Organic Frameworks -- Upconversion Luminescence; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202216269
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Lanthanide‐doped metal–organic frameworks (Ln‐MOFs) have versatile luminescence properties, however it is challenging to achieve lanthanide‐based upconversion luminescence in these materials. Here, 1, 3, 5‐benzenetricarboxylic acid (BTC) and trivalent Yb 3+ ions were used to generate crystalline Yb‐BTC MOF 1D‐microrods with upconversion luminescence under near infrared excitation via cooperative luminescence. Subsequently, the Yb‐BTC MOFs were doped with a variety of different lanthanides to evaluate the potential for Yb 3+ ‐based upconversion and energy transfer. Yb‐BTC MOFs doped with Er 3+, Ho 3+, Tb 3+, and Eu 3+ ions exhibit both the cooperative luminescence from Yb 3+ and the characteristic emission bands of these ions under 980 nm irradiation. In contrast, only the 497 nm upconversion emission band from Yb 3+ is observed in the MOFs doped with Tm 3+, Pr 3+, Sm 3+, and Dy 3+ . The effects of different dopants on the efficiency of cooperative luminescence were established and will provide guidance for the exploitation of Ln‐MOFs exhibiting upconversion. Abstract : 1, 3, 5‐Benzenetricarboxylic acid (BTC) and Yb 3+ ions were assembled into Yb‐BTC metal–organic frameworks (Yb‐BTC MOFs) showing upconversion luminescence under near‐infrared excitation via cooperative luminescence. In addition, various activators were doped into the Yb‐BTC MOFs and their upconversion luminescence and energy‐transfer mechanisms were studied. These MOFs show excellent potential for optical information storage.