Copper carbide composite catalyst for hydrogenolysis of glycerol to 1, 2-propanediol. (15th February 2023)

• Record Type: Journal Article
• Authors: Liu, Shan; Yu, Zhiquan; Lu, Chenyang; Wang, Yao; Sun, Fanfei; Sun, Zhichao; Liu, Yingya; Shi, Chuan; Wang, Anjie
• Is Part Of: Fuel. Volume 334(2023)Part 2
• Publication Date: 2023-02-15
• Subjects: Hydrogenolysis -- Glycerol -- 1, 2-Propanediol -- Copper carbide -- ZnO -- Microchannel reaction system; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2022.126763
• Languages: English
• ISSNs: 0016-2361

Abstract

Graphical abstract: Highlights: Cux C-Cu was obtained by reacting Cu(OH)2 with C2 H2 /Ar and subsequent H2 reduction. Cux C-Cu showed significantly higher hydrogenation activity than Cu metal. The addition of ZnO led to improved dispersion and catalytic performance. Cux C-Cu-ZnO composite catalyst performed well in glycerol hydrogenolysis. Abstract: The hydrogenolysis of renewable glycerol towards 1, 2-propanediol (abbreviate as 1, 2-PDO) has been a promising approach. In this work, high-performance catalysts containing copper carbide (Cux C) were prepared by the following procedure: (1) synthesis of Cu(OH)2 -Zn(OH)2 mixture via a microchannel reaction system, (2) thermal treatment at 100 °C in 0.50 vol% C2 H2 /Ar gas, and (3) reduction at 300 °C under H2 atmosphere. The continuous synthesis of Cu(OH)2 -Zn(OH)2 mixture in a microchannel reaction system yielded highly dispersed precursors, and the addition of ZnO led to improved dispersion of copper species with enhanced acidity. The new crystal phase, copper carbide (Cux C), was generated through reacting Cu(OH)2 particles with C2 H2 /Ar and subsequent hydrogen reduction. Cux C exhibited significantly higher hydrogenation activity than Cu metal, and contributed to enhanced catalytic activity for continuous glycerol hydrogenolysis in the fixed-bed reactor. Copper carbide composite catalyst (Cu/Zn = 8) afforded 100 % glycerol conversion and high selectivity (92.3 %) towards 1, 2-PDO at 240 °C, 2.0 MPa and WHSV 3 h −1 .