Σ-Hole triel bonds in aluminium derivatives. Issue 3 (3rd January 2023)

• Record Type: Journal Article
• Authors: Tabernero, Vanessa; Teresa Muñoz, M.; Palenzuela, Miguel; Gomila, Rosa M.; Frontera, Antonio; Mosquera, Marta E. G.
• Is Part Of: Dalton transactions. Volume 52:Issue 3(2023)
• Page Start: 551
• Page End: 555
• Publication Date: 2023-01-03
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt03581b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The synthesis, X-ray characterization and DFT study of a new mononuclear aluminium compound exhibiting an intramolecular σ-hole triel bonding interaction is described. Abstract : This communication reports the synthesis and X-ray characterization of a new mononuclear aluminium compound exhibiting an intramolecular σ-hole triel bonding interaction. It is compared with a dinuclear aluminium compound, previously reported by us, where the aluminium atoms participate in two concurrent σ-hole triel bonding interactions. To our knowledge, such behaviour has not been previously described in the literature.