Dual Hybridized Local and Charge Transfer Characteristic Fluorophore as an Efficient Nondoped Emitter for Electroluminescent Device. Issue 1 (17th October 2022)

• Record Type: Journal Article
• Authors: Sudyoadsuk, Taweesak; Petdee, Sujinda; Waengdongbung, Wijitra; Loythaworn, Thidarat; Chasing, Pongsakorn; Kongsabay, Suwapat; Therdkatanyuphong, Pattarawadee; Promarak, Vinich
• Is Part Of: Advanced photonics research. Volume 4:Issue 1(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-10-17
• Subjects: benzothiadiazole -- carbazole -- dual-hybridized local and charge transfer -- organic light-emitting diodes -- solution processes; Photonics -- Periodicals; 621.36505
• DOI: 10.1002/adpr.202200195
• Languages: English
• ISSNs: 2699-9293

Abstract

Abstract : Hybridized local and charge transfer (HLCT) is an attractive strategy for achieving efficient electroluminescence (EL) in electrofluorescent devices by the conversion of triplet‐state (T) to singlet‐state (S) excitons via a reverse intersystem crossing, giving rise to a high exciton utilization efficiency exceeding the spin statistical limit. Excellent device performance is reached using thermally evaporated emissive layers. However, for potential large‐scale commercialization, it is crucial to attain comparable device performances using low‐cost solution‐processing techniques. Herein, a new concept of dual HLCT characteristic fluorophore (BCBF ) with a high solid‐state fluorescence as a nondoped emitter for a simple structured solution‐processed EL device is presented. BCBF is effectively formulated by π‐conjugation linking two HLCT fragments with a highly soluble hole‐transporting aromatic moiety. Its dual HLCT and photoluminescence (PL) properties are experimentally and theoretically probed by the solvatochromic effect and density functional theory (DFT) calculations. The molecule exhibits an intense yellow–green emission with a good solution‐processed film‐forming quality and a high solid‐state fluorescence quantum yield of 80%. BCBF is successfully utilized as a nondoped emissive layer in a solution‐processed double‐layered organic light‐emitting diode (OLED), which shows excellent EL performance (brightness of 47 580 cd m −2, current efficiency of 15.78 cd A −1, and external quantum efficiency of 7.20%). Abstract : Herein, a new concept of dual hybridized local and charge transfer (HLCT) characteristic fluorophore as a high solid‐state fluorescence emitter is presented. Its simple solution‐processed organic light‐emitting diode (OLED) exhibits excellent performance (maximum brightness of 47 580 cd m −2, maximum current efficiency of 15.78 cd A −1, and maximum external quantum efficiency of 7.20%).