Synthesis, and spectroscopic, thermal and dielectric properties of phosphazene based ionic liquids: OFET application and tribological behavior. (8th January 2019)

• Record Type: Journal Article
• Authors: Akbaş, Hüseyin; Karadağ, Ahmet; Destegül, Ali; Çakırlar, Çiğdem; Yerli, Yusuf; Tekin, Kadir Cihan; Malayoğlu, Uğur; Kılıç, Zeynel
• Is Part Of: New journal of chemistry. Volume 43:Number 5(2019)
• Page Start: 2098
• Page End: 2110
• Publication Date: 2019-01-08
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c8nj04948c
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Mono(4-fluorobenzyl)cyclotriphosphazene derivatives with (dimethylamino)ethoxy (Pz1a–2a ) and (dimethylamino)propoxy (Pz1b–2b ) chains and their ionic liquids (PzIL1–PzIL4 and PzIL1a–PzIL4a ) were synthesized. Abstract : Mono(4-fluorobenzyl)cyclotriphosphazene derivatives with (dimethylamino)ethoxy (Pz1a–2a ) and (dimethylamino)propoxy (Pz1b–2b ) chains were synthesized. The chain nitrogen atoms of fully substituted cyclotriphosphazene compounds were quaternized by treatment with CH3 I to give phosphazene based ionic liquids (PzILs), PzIL1–PzIL4 . Subsequent metathesis with LiN(SO2 CF3 )2 gave the salts, PzIL1a–PzIL4a . The structures of the PzILs were confirmed by elemental analyses, FTIR and 1 H, 13 C{ 1 H}, and 31 P{ 1 H} NMR techniques. The thermal properties of all compounds were described using thermogravimetric analysis (TGA). These newly synthesized PzILs were used as the dielectric layer in organic field effect transistors (OFETs). Both dielectric and OFET characterization were performed. Because of the high dielectric effect of the PzILs, the fabricated OFETs operated in the low voltage range. Furthermore, a sliding wear test was conducted at room temperature using an AA7075 disc specimen against a stationary 100Cr6 steel ball. The wear protection of the PzILs and 15W40 engine oil was determined by considering the volume loss of AA7075. The lowest coefficient of friction (COF) and wear loss were obtained with PzIL4a .