Evaluation of Cathode Materials with Lithium-Metal Anodes: Baseline Performance and Protocol Standardization of Coin Cells. Issue 1 (1st January 2023)

• Record Type: Journal Article
• Authors: Tornheim, Adam; O'Hanlon, Daniel C.; Vu, Anh; Gim, Jihyeon; Abraham, Daniel P.; Croy, Jason R.
• Is Part Of: Journal of the Electrochemical Society. Volume 170:Issue 1(2023)
• Publication Date: 2023-01-01
• Subjects: Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/1945-7111/acada4
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : The collaborative evaluation of electrode materials across multiple research entities requires standardized electrochemical testing protocols to produce reliable, one-to-one comparisons between different systems of interest. Similar to the work done by Long et al. on protocol standardization for coin-cell testing with graphite anodes [ J. Electrochem. Soc., 163, A2999, (2016)], we introduce two standardized testing protocols designed to quickly evaluate important electrochemical properties of cathode materials using lithium-metal anodes. The two protocols measure kinetic and thermodynamic capacity losses, rate- and voltage-dependent cycling capacities, instabilities at high voltage and high cycling rate, and overpotentials at various states of charge. We then apply these protocols to four commercially available cathode materials to establish benchmark performance metrics that can be used to screen and evaluate new cathode materials.