Study on the corrosion of refractory materials by coal blended with the extraction residue of direct coal liquefaction in a simulated gasification atmosphere. Issue 4 (1st November 2021)

• Record Type: Journal Article
• Authors: Peng, Baozi; Zhao, Shixian; Liu, Zhen
• Is Part Of: Clean energy. Volume 5:Issue 4(2021)
• Page Start: 731
• Page End: 740
• Publication Date: 2021-11-01
• Subjects: corrosion -- gasification -- refractory -- slag -- direct coal liquefaction residue -- extraction residue; Clean energy -- Periodicals; Energy industries -- Periodicals; Renewable energy sources -- Periodicals; Carbon dioxide mitigation -- Periodicals; Green technology -- Periodicals; Carbon dioxide mitigation; Clean energy; Energy industries; Green technology; Renewable energy sources; Electronic journals; Periodicals
• DOI: 10.1093/ce/zkab045
• Languages: English
• ISSNs: 2515-396X

Abstract

Abstract: Utilizing the extraction residue (ER) of direct coal liquefaction residue as a gasification feedstock has significant economic value. But the characteristic of high ash and iron in the ER would increase the risk of corrosion of the refractory materials and affect the long-term operation of the gasifier. In this work, corrosion experiments of molten slag derived from a mixture of 20 wt% ER and 80 wt% coal on a high-chromia refractory brick and SiC brick were carried out using a rotary-drum furnace in a simulated gasification atmosphere. The experimental results show that the viscosity of the poured slag is larger as compared to the initial ash sample at the same temperature, which suggests that the viscosity–temperature relationship of the poured slag should be used as the reference for the operation temperature of the gasifier to ensure that the slag can flow during operation. For a high-chromia refractory brick, iron oxides in molten slag could react with Cr2 O3 in the refractory matrix but, because the aggregate was not found to be damaged, the damage to the matrix structure was the key factor for causing the corrosion of the high-chromia refractory brick. Metallic iron was observed in the exposed SiC brick, which indicated that the reaction between the iron oxides in the slag and SiC occurred, forming metallic iron and SiO2 . The corrosion of a SiC brick by molten slag depended mainly on the dissolution of Al2 O3 particles and the reaction between iron oxides in the molten slag and SiC particles. Therefore, the high iron content in coal ash had a serious influence on the corrosion of refractory materials. More efforts need to be made on coal blended with ER as a gasification feedstock in the future. Abstract : The extraction residue (ER) of direct coal liquefaction has significant economic value as a gasification feedstock, but increased corrosion of the refractory lining of the gasifier could result. Lab-scale experiments on the interaction between coal ash/ER mixtures and refractory materials were carried out in this study. Graphical Abstract: