Mechanism of ammonia oxidation to dinitrogen, nitrite, and nitrate on β‐Ni(OH)2 from first‐principles simulations. Issue 6 (27th October 2021)

• Record Type: Journal Article
• Authors: Choueiri, Rachelle M.; Tatarchuk, Stephen W.; Klinkova, Anna; Chen, Leanne D.
• Is Part Of: Electrochemical science advances. Volume 2:Issue 6(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-10-27
• Subjects: ammonia oxidation reaction -- density functional theory -- electrocatalysis -- nickel hydroxide; Electrochemistry -- Periodicals; Electrochemistry; Periodicals; 541.3705
• DOI: 10.1002/elsa.202100142
• Languages: English
• ISSNs: 2698-5977

Abstract

Abstract: The electrocatalyzed ammonia oxidation reaction (AOR) is a potential pathway toward waste ammonia remediation, energy generation, and the synthesis of value‐added products. To date, mechanistic studies have focused on elucidating the progress of AOR on Pt‐based catalysts with an established pathway for N 2 $\mathrm{N_2}$ only. In this work, density functional theory was applied to determine the lowest energy intermediates toward nitrogen gas, nitrite, and nitrate formation on β $\beta$ ‐ Ni ( OH ) 2 $\mathrm{Ni(OH)_2}$, a promising electrocatalyst material for AOR. It was found that dinitrogen formation progresses via NH‐NH coupling, whereas nitrite and nitrate formation occurs via deprotonation of ammonia to form adsorbed N and subsequent hydroxylation to form oxygenated intermediates. This work is the first to report a mechanism for nitrite and nitrate formation and will also serve as a benchmark for future studies on Ni‐based materials.