Frontispiece: Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances. Issue 62 (7th November 2022)

• Record Type: Journal Article
• Authors: Grau, Benedikt W.; Neuhauser, Alexander; Aghazada, Sadig; Meyer, Karsten; Tsogoeva, Svetlana B.
• Is Part Of: Chemistry. Volume 28:Issue 62(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-07
• Subjects: iron catalysis -- ligands -- metathesis catalysts -- olefin metathesis -- olefins; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202286261
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Olefin metathesis gives access to important petrochemicals, polymers, and pharmaceuticals. The catalysts for these transformations are often based on high‐valent metal ions e.g., Ru(IV), which have been improved through ligand modifications. An attractive, but challenging goal is to catalyze olefin metathesis with a non‐toxic, bio‐compatible, and abundant element; namely, iron . Indeed, the first pieces of evidence suggest that low‐valent Fe(II) complexes are active in olefin metathesis. This Review by K. Meyer, S. B. Tsogoeva, et al. (DOI: 10.1002/chem.202201414 ) summarizes the key advances and challenges in this endeavor.