Cover Feature: Heterobimetallic Gold/Ruthenium Complexes Synthesized via Post‐functionalization and Applied in Dual Photoredox Gold Catalysis (Chem. Eur. J. 57/2022). Issue 57 (26th September 2022)

• Record Type: Journal Article
• Authors: Bayer, Lea; Birenheide, Bernhard S.; Krämer, Felix; Lebedkin, Sergei; Breher, Frank
• Is Part Of: Chemistry. Volume 28:Issue 57(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-09-26
• Subjects: bimetallic complexes -- cooperative effects -- metalloligands -- photoredox catalysts -- post-functionalization; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202202777
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Enjoying the sun : The cover illustrates the potential of heterobimetallic Au I /Ru II complexes to facilitate the P arylation of H‐phosphonates with diazonium salts, while visible light kicks off the dual gold and photoredox catalytic cycle. The underlying structure of the catalysts' coordinating ligand system is accessible by a novel postfunctionalization approach, and the stereochemistry can be controlled by the order of metal coordination and click reaction. More information can be found in the Research Article by F. Breher and co‐workers (DOI: 10.1002/chem.202201856 ).