Rhodium‐catalyzed Decarbonylation of Acylsilanes. Issue 12 (29th November 2022)

• Record Type: Journal Article
• Authors: Yoshida, Tomoki; Kodama, Takuya; Tobisu, Mamoru
• Is Part Of: Asian journal of organic chemistry. Volume 11:Issue 12(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-29
• Subjects: Acylsilanes -- Decarbonylation -- Homogeneous catalysis -- Organosilicon compounds -- Rhodium catalyst; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.202200610
• Languages: English
• ISSNs: 2193-5807

Abstract

Abstract: The rhodium‐catalyzed decarbonylation of acylsilanes is reported. This reaction proceeds through the cleavage of a carbon–silicon bond in acylsilanes. When two different acylsilanes are reacted in one batch, crossover products are formed. These results indicate that two mechanisms are operating in this catalytic reaction. Abstract : A carbon –silicon bond in acylsilanes can be activated by a rhodium(I) catalyst. A rhodium‐catalyzed decarbonylation of acylsilane is developed for the formation of arylsilanes.