Investigation of Water Splitting Reaction by a Multicopper Oxidase through X‐ray Absorption Nanospectroelectrochemistry (Adv. Energy Mater. 47/2022). Issue 47 (15th December 2022)

• Record Type: Journal Article
• Authors: Sedenho, Graziela C.; Neckel, Itamar T.; Colombo, Rafael N. P.; Pacheco, Jéssica C.; Bertaglia, Thiago; Crespilho, Frank N.
• Is Part Of: Advanced energy materials. Volume 12:Issue 47(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-12-15
• Subjects: bioelectrocatalysis -- microspectroelectrochemistry -- multicopper oxidases -- water oxidation -- X‐ray absorption spectroscopy; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202270201
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : Water Splitting The water oxidation reaction catalyzed by bilirubin oxidase demonstrates an inverse proton dependence relative to the native oxygen reduction reaction. In article number 2202485, Frank N. Crespilho, and co‐workers demonstrate the high‐valent copper character of the enzyme active site during the water oxidation bioelectrocatalysis through X‐ray absorption nanospectroelectrochemistry.