Electrocatalytic enhancement mechanism of cobalt single atoms anchored on different MXene substrates in oxygen and hydrogen evolution reactions. Issue 2 (23rd October 2022)

• Record Type: Journal Article
• Authors: Zhao, Xin; Zheng, Xuerong; Lu, Qi; Li, Ying; Xiao, Fengping; Tang, Bing; Wang, Shixun; Yu, Denis Y. W.; Rogach, Andrey L.
• Is Part Of: EcoMat. Volume 5:Issue 2(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-10-23
• Subjects: Co single‐atom catalyst -- hydrogen evolution -- MXene substrates -- oxygen evolution -- water splitting; Materials -- Environmental aspects -- Periodicals; Clean energy -- Periodicals; 621.042
• DOI: 10.1002/eom2.12293
• Languages: English
• ISSNs: 2567-3173

Abstract

Abstract: Decorating single atoms of transition metals on MXenes to enhance the electrocatalytic properties of the resulting composites is a useful strategy for developing efficient electrocatalysts, and the mechanisms behind this enhancement are under intense scrutiny. Herein, we anchored Co single atoms onto several commonly used MXene substrates (V2 CTx, Nb2 CTx and Ti3 C2 Tx ) and systematically studied the electrocatalytic behavior and the mechanisms of oxygen and hydrogen evolution reactions (OER and HER, respectively) of the resulting composites. Co@V2 CTx composite displays an OER overpotential of 242 mV and an HER overpotential of 35 mV at 10 mA cm −2 in 1.0 M KOH electrolyte, which is much lower than for Co@Nb2 CTx and Co@Ti3 C2 Tx, making it comparable to the commercial noble metal Pt/C and RuO2 /C electrocatalysts. The experimental and theoretical results point out that the enhanced bifunctional catalytic performance of Co@V2 CTx benefits from the stronger hybridization between Co 3d and surface terminated O 2p orbitals which optimized the electronic structure of Co single atoms in the composite. This, in turn, results in lowering the OER and HER energy barriers and acceleration of the catalytic kinetics in case of the Co@V2 CTx composite. The advantage of Co@V2 CTx was further validated by its high overall water splitting performance (1.60 V to deliver 10 mA cm −2 ). Our study sheds light on the origins of the catalytic activity of single transition metals atoms on MXene substrates, and provides guidelines for designing efficient bifunctional MXene‐based electrocatalysts. Abstract : Co single atoms were anchored on three different MXenes substrates, namely Co@V2 CTx, Co@Nb2 CTx and Co@Ti3 C2 2Tx, which were tested as electrocatalysts of oxygen and hydrogen evolution reactions (OER and HER). Combinations of experimental and theoretical studies point out that the enhanced bifunctional catalytic performance of Co@V2 CTx benefits from the higher electron transfer, which results in lowering the energy barriers and accelerating the catalytic kinetics for both OER and HER.