Analysis of Permeation of Low‐Molecular‐Weight Hydrocarbons through Polyolefins for Testing of a New Developed Method. Issue 24 (11th November 2022)

• Record Type: Journal Article
• Authors: Berger, Katrin; Riess, Gisbert
• Is Part Of: Macromolecular chemistry and physics. Volume 223:Issue 24(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-11-11
• Subjects: GC‐MS -- low‐molecular‐weight hydrocarbons -- oil and gas -- permeation -- pipes; Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.202200208
• Languages: English
• ISSNs: 1022-1352

Abstract

Abstract: In onshore oil and gas industries polymers are considered as a potential pipe material. One special aspect in this field of application is the resistance of the material against the permeation of low‐molecular‐weight hydrocarbons. These small molecules may permeate through the material and cause environmental problems. In this contribution, the main influencing parameters on the permeation process of low‐molecular‐weight hydrocarbons through hig‐density polyethylene (HDPE a) re investigated by gravimetric analysis. To bypass the limitations of this well‐established method a new measuring method based on gas chromatography‐mass spectroscopy (GC‐MS) techniques is developed. The main advantages of the newly developed system are demonstrated by test measurements of filled polyethylene (PE) pipes. The comparison of the calculated permeation rates of the tested hydrocarbons using both measuring methods showed a good accordance of the results. Abstract : The results of this GC‐MS method show a good agreement with the data of the well‐established gravimetric investigations. The new permeation method is applicable on pipes, which are already in use in oil and gas fields. It is a nondestructive and timesaving technique, where the detection of all permeating individual hydrocarbons is possible.