Self‐Assembled Networks for Regulating Lithium Polysulfides in Lithium‐Sulfur Batteries. Issue 23 (18th October 2022)

• Record Type: Journal Article
• Authors: Wang, Zhihua; Liu, Yilin; Ni, Junze; You, Yingying; Cai, Yingying; Zhang, Hanping
• Is Part Of: ChemSusChem. Volume 15:Issue 23(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-10-18
• Subjects: electrochemistry -- energy storage -- lithium-sulfur battery -- self-assembly -- shuttle effect; Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.202201670
• Languages: English
• ISSNs: 1864-5631

Abstract

Abstract: Inhibiting the shuttle effect caused by soluble lithium polysulfides (LiPSs) is of importance for lithium‐sulfur (Li−S) batteries. Here, a strategy was developed to construct protective layers by self‐assembly networks to regulate the LiPSs. 2, 5‐Dichloropyridine (25DCP) holds two kinds of functional groups. Among them, the two C−Cl bonds were nucleophilic substituted by S in LiPSs to form long chains. The pyridine N interacted with Li in other LiPSs via Li bonds to form a short chain. As a result, the long chains were cross‐linked by the short chain to form an insoluble network. The as‐prepared network covered the sulfur electrode interface to suppress the shuttle effect of the subsequently generated LiPSs. Furthermore, 25DCP improved the redox dynamics by changing the energy level and electronic structure of the sulfur species. Therefore, the Li−S batteries with 25DCP exhibited good electrochemical performance. This work provides a feasible strategy for regulating the LiPSs. Abstract : Self‐assembly : 2, 5‐Dichloropyridine (25DCP), which contains nucleophilic and electrophilic heterogeneity, binds to lithium polysulfides to construct long and short chains, respectively. Two types of chains form insoluble networks through self‐crosslinking at the electrode‐electrolyte interface to inhibit the "shuttle effect".