Simple cleaning and regeneration of tip‐enhanced Raman spectroscopy probe with UV sources. (7th September 2022)

• Record Type: Journal Article
• Authors: Zhang, Kaifeng; Taniguchi, Shin‐ichi; Saeki, Tomonori; Bao, Yifan; Cao, Maofeng; Watanabe, Masahiro; Wang, Xiang; Kobayashi, Kei; Ren, Bin; Yamada, Hirofumi
• Is Part Of: Journal of Raman spectroscopy. Volume 53:Number 12(2022)
• Page Start: 2023
• Page End: 2030
• Publication Date: 2022-09-07
• Subjects: atomic force microscope (AFM) -- thin‐film waveguide probe -- tip regeneration -- tip‐enhanced Raman spectroscopy (TERS) -- UV cleaning; Raman spectroscopy -- Periodicals; 535.846
• DOI: 10.1002/jrs.6440
• Languages: English
• ISSNs: 0377-0486

Abstract

Abstract: Tip‐enhanced Raman spectroscopy (TERS) is a powerful nano‐optical approach that allows the extraction of nanometer resolved chemical information. The key to a successful TERS measurement is the quality of the TERS tip. However, tip contamination, which usually occurs during measurements on samples that include organic molecules or after long‐term storage, remains a critical problem for TERS experiments. It not only affects the reliability of TERS results but also hinders the long‐term development of the TERS technique. Herein, we propose a method that enables the regeneration of contaminated TERS tips. For this purpose, we prepared a TERS tip contaminated by stable organic molecules, which was subjected to a simple and rapid ultraviolet (UV) cleaning procedure to remove the contaminants and to regenerate the tip. This method is demonstrated to be effective in removing the contaminants from the TERS tip by directly breaking the bonds in the contaminated molecules and oxidizing organic compounds with the generated reactive oxygen atom. This simple method could propel the development of the TERS technique. Abstract : A simple method for cleaning and regenerating TERS tips with UV light irradiation.