Palladium incorporated MIL-101(Cr): a heterogeneous and reusable catalyst for the C–H functionalization of unactivated arenes. (23rd November 2022)

• Record Type: Journal Article
• Authors: Sarkar, Fillip Kumar; Gajurel, Sushmita; Kyndiah, Lenida; Sarkar, Rajib; Devan, Rupesh S.; Pal, Amarta Kumar
• Is Part Of: New journal of chemistry. Volume 46:Number 48(2022)
• Page Start: 23102
• Page End: 23111
• Publication Date: 2022-11-23
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d2nj03889g
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Palladium incorporated MIL-101(Cr) as an efficient heterogeneous catalyst has been developed for the C–H functionalization of unactivated arenes. Abstract : Herein, a palladium containing metal–organic framework was designed for use in the C–H functionalization of unactivated arenes. The catalyst was prepared via post-synthetic modification of amino-functionalized MIL-101(Cr) and was well characterized using spectroscopic techniques. The catalyst is highly active in the aforementioned reaction, resulting in a 70–92% yield of the desired products at room temperature. Mild reaction conditions, gram-scale synthesis, easy recovery, and reusability of the catalyst add sustainable advantages to the protocol.