Triple dehydrofluorination as a route to amidine-functionalized, aromatic phosphorus heterocycles. Issue 98 (10th November 2022)
- Record Type:
- Journal Article
- Title:
- Triple dehydrofluorination as a route to amidine-functionalized, aromatic phosphorus heterocycles. Issue 98 (10th November 2022)
- Main Title:
- Triple dehydrofluorination as a route to amidine-functionalized, aromatic phosphorus heterocycles
- Authors:
- Coles, Nathan T.
Groth, Lucie J.
Dettling, Lea
Frost, Daniel S.
Rigo, Massimo
Neale, Samuel E.
Müller, Christian - Abstract:
- Abstract : Hitherto unknown amidine-functionalized phosphabenzenes selectively form by a cascade of dehydrofluorination reactions. Abstract : An unexpected route to hitherto unknown amidine-functionalized phosphinines has been developed that is rapid and simple. Starting from primary amines and CF3 -substituted λ 3, σ 2 -phosphinines, a cascade of dehydrofluorination reactions leads selectively to ortho -amidinephosphinines. DFT calculations reveal that this unusual transformation can take place via a series of nucleophilic attacks at the electrophilic, low-coordinate phosphorus atom.
- Is Part Of:
- Chemical communications. Volume 58:Issue 98(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 98(2022)
- Issue Display:
- Volume 58, Issue 98 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 98
- Issue Sort Value:
- 2022-0058-0098-0000
- Page Start:
- 13580
- Page End:
- 13583
- Publication Date:
- 2022-11-10
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc05178h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 24668.xml