Dual NHC/photoredox catalytic synthesis of 1, 4-diketones using an MR-TADF photocatalyst (DiKTa). Issue 98 (21st November 2022)

• Record Type: Journal Article
• Authors: Prentice, Callum; Morrison, James; Zysman-Colman, Eli; Smith, Andrew D.
• Is Part Of: Chemical communications. Volume 58:Issue 98(2022)
• Page Start: 13624
• Page End: 13627
• Publication Date: 2022-11-21
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc05705k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The use of the recently reported organic multi-resonant thermally activated delayed fluorescent (MR-TADF) photocatalyst DiKTa allows for the modular synthesis of 1, 4-diketones under mild and metal-free conditions. Abstract : The use of the recently reported organic multi-resonant thermally activated delayed fluorescence (MR-TADF) photocatalyst DiKTa allows for the modular synthesis of 1, 4-diketones under mild and metal-free conditions. The reaction proceeds via a three-component relay process in the presence of an N-heterocyclic carbene (NHC) organocatalyst.