Cover Feature: Multistimuli‐Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches (Chem. Eur. J. 61/2021). Issue 61 (13th September 2021)

• Record Type: Journal Article
• Authors: Birenheide, Bernhard S.; Krämer, Felix; Bayer, Lea; Mehlmann, Paul; Dielmann, Fabian; Breher, Frank
• Is Part Of: Chemistry. Volume 27:Issue 61(2021)
• Page Start: 15015
• Page End: 15015
• Publication Date: 2021-09-13
• Subjects: bimetallic complexes -- cooperative effects -- ferrocenophane -- metalloligands -- stimuli-responsive ligands; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202103251
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : A retro‐style arcade machine needs an oxidant or a proton to be inserted to start playing and to switch the donating capabilities of novel phosphine ligands orthogonally and reversibly. Rh‐catalysed hydrosilylation showed that these triggers can influence either the rate of conversion and/or the product distribution. The Japanese kanji for "iron" highlights the ferrocene moiety in the ligands′ metal complexes. More information can be found in the Communication by F. Dielmann, F. Breher et al. (DOI: 10.1002/chem.202101969 ).