Rhodium-catalyzed formal [2 + 2 + 1] annulation of arylboronic acids with alkynes. Issue 24 (9th November 2022)
- Record Type:
- Journal Article
- Title:
- Rhodium-catalyzed formal [2 + 2 + 1] annulation of arylboronic acids with alkynes. Issue 24 (9th November 2022)
- Main Title:
- Rhodium-catalyzed formal [2 + 2 + 1] annulation of arylboronic acids with alkynes
- Authors:
- Wang, Chenhong
Wu, Changhui
Yang, Yiming
Xing, Junhao
Dou, Xiaowei - Abstract:
- Abstract : A novel rhodium-catalyzed formal [2 + 2 + 1] annulation of alkynes with arylboronic acids to produce 1, 1-disubstituted 1( H )-indenes is developed. Abstract : A Rh(i )-catalyzed formal [2 + 2 + 1] annulation between arylboronic acids and alkynes for the expedient synthesis of indenes is described. A reaction process involving intermolecular carborhodation, 1, 4-Rh migration, and intramolecular carborhodation, which forges three C–C bonds of the indene core, is proposed for the reaction outcome.
- Is Part Of:
- Organic chemistry frontiers. Volume 9:Issue 24(2022)
- Journal:
- Organic chemistry frontiers
- Issue:
- Volume 9:Issue 24(2022)
- Issue Display:
- Volume 9, Issue 24 (2022)
- Year:
- 2022
- Volume:
- 9
- Issue:
- 24
- Issue Sort Value:
- 2022-0009-0024-0000
- Page Start:
- 6915
- Page End:
- 6919
- Publication Date:
- 2022-11-09
- Subjects:
- Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/qo#!recentarticles&all ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2qo01464e ↗
- Languages:
- English
- ISSNs:
- 2052-4110
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6287.121000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 24612.xml