Efficient and Stable Perovskite Solar Cells by Fluorinated Ionic Liquid–Induced Component Interaction. Issue 1 (27th November 2020)

• Record Type: Journal Article
• Authors: Wang, Yue; Chao, Lingfeng; Niu, Tingting; Li, Deli; Wei, Qi; Wu, Hui; Qiu, Jian; Lu, Hui; Ran, Chenxin; Zhong, Qi; Song, Lin; Xing, Guichuan; Xia, Yingdong; Chen, Yonghua; Müller‐Buschbaum, Peter; Huang, Wei
• Is Part Of: Solar RRL. Volume 5:Issue 1(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-11-27
• Subjects: component interaction -- fluorinated ionic liquids -- perovskite solar cells -- stability; Solar energy -- Periodicals; Photovoltaic power generation -- Periodicals; Solar energy -- Research -- Periodicals; Photovoltaic power generation -- Research -- Periodicals; Periodicals; 333.7923
• DOI: 10.1002/solr.202000582
• Languages: English
• ISSNs: 2367-198X

Abstract

Abstract : The instability of organic cations in lead halide perovskite materials is a major obstacle for the commercial breakthrough of perovskite photovoltaics due to desorption of organic cations during the thermal annealing and device operation. Herein, a novel strategy is reported to improve the performance and stability of organic halide perovskite solar cells containing organic cations by adding a small amount of the ionic liquid methylammonium difluoroacetate (MA + DFA − ). Nuclear magnetic resonance and Fourier‐transform infrared spectroscopy measurements show that MA + DFA − can anchor the organic cations via hydrogen bonding and enhance the Pb–O interaction in perovskite precursors, leading to the retardation of the perovskite crystallization and improved stability of the perovskite precursor solution. Dynamic light scattering and scanning electron microscopy verify the defect‐passivation effect of MA + DFA − on the perovskite precursors and films. The passivated perovskite film shows superior photo carrier dynamics as investigated by time‐resolved photoluminescence and transient absorption spectra. Moreover, the hydrogen bonding of the perovskite with MA + DFA − imparts excellent ambient and thermal stability to the film as revealed by X‐ray diffraction measurements. As a result, devices with a high efficiency of 21.46% and excellent stability over 180 days in nitrogen atmosphere at room temperature are achieved with the ionic liquid. Abstract : Herein, a small amount of the ionic liquid methylammonium difluoroacetate is introduced to anchor the organic cations via hydrogen bonding and to enhance the Pb–O interaction in perovskite precursors for efficient and stable solar cells.