Investigation of Room Temperature Formation of the Ultra‐Hard Nanocarbons Diamond and Lonsdaleite. Issue 50 (4th November 2020)

• Record Type: Journal Article
• Authors: McCulloch, Dougal G.; Wong, Sherman; Shiell, Thomas B.; Haberl, Bianca; Cook, Brenton A.; Huang, Xingshuo; Boehler, Reinhard; McKenzie, David R.; Bradby, Jodie E.
• Is Part Of: Small. Volume 16:Issue 50(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-11-04
• Subjects: diamond -- lonsdaleite -- microscopy -- shear -- synthesis; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202004695
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: Diamond is an attractive material due to its extreme hardness, high thermal conductivity, quantum optical, and biomedical applications. There is still much that is not understood about how diamonds form, particularly at room temperature and without catalysts. In this work, a new route for the formation of nanocrystalline diamond and the diamond‐like phase lonsdaleite is presented. Both diamond phases are found to form together within bands with a core‐shell structure following the high pressure treatment of a glassy carbon precursor at room temperature. The crystallographic arrangements of the diamond phases revealed that shear is the driving force for their formation and growth. This study gives new understanding of how shear can lead to crystallization in materials and helps elucidate how diamonds can form on Earth, in meteorite impacts and on other planets. Finally, the new shear induced formation mechanism works at room temperature, a key finding that may enable diamond and other technically important nanomaterials to be synthesized more readily. Abstract : Diamond synthesis at room temperature from a glassy carbon precursor is demonstrated. Diamond normally forms from solid carbon under high pressure and high temperature conditions. By compressing glassy carbon in a diamond anvil cell without heating, this article shows how the presence of shear leads to the formation of nanocrystalline diamond and lonsdaleite (hexagonal diamond).