Zinc hydroxystannate/zinc-tin oxide heterojunctions for the UVC-assisted photocatalytic degradation of methyl orange and tetracycline. (1st January 2023)

• Record Type: Journal Article
• Authors: Kumar, Navneet; Jung, Uijin; Jung, Bomseumin; Park, Jinsub; Naushad, Mu.
• Is Part Of: Environmental pollution. Volume 316(2023)part 1
• Publication Date: 2023-01-01
• Subjects: Zinc hydroxystannate -- Zinc-tin oxide -- Dye degradation -- Antibiotic degradation -- Photocatalysis -- Tetracycline; Pollution -- Periodicals; Pollution -- Environmental aspects -- Periodicals; Environmental Pollution -- Periodicals; Pollution -- Périodiques; Pollution -- Aspect de l'environnement -- Périodiques; Pollution -- Effets physiologiques -- Périodiques; Pollution; Pollution -- Environmental aspects; Periodicals; Electronic journals; 363.73
• DOI: 10.1016/j.envpol.2022.120353
• Languages: English
• ISSNs: 0269-7491

Abstract

Abstract: Partial phase modification of zinc hydroxystannate (ZHS) is an effective technique for improving its light absorption capacity. In this study, a zinc hydroxystannate/zinc-tin oxide (ZHS/ZTO) heterostructure was synthesized via chemical co-precipitation followed by annealing. The as-prepared heterostructure revealed cubic crystal morphology along with high-intensity diffraction peaks in the XRD pattern. The XPS analysis of ZHS/ZTO heterostructures demonstrated the presence of key elements (Zn, Sn, and O) in their most stable ionic forms. The photocatalytic degradation efficiencies of the prepared samples were tested against methyl orange (MO) and tetracycline (TC) in an aqueous medium under UVC (254 nm) radiation. Under optimized conditions, maximum degradation efficiencies of 99% for MO and 97% for TC were observed in 120 and 180 min, respectively. Further, the predominant role of OH˙ radicals in the photocatalytic removal of MO and TC was evident through scavenging experiments. 2nd order kinetic model was outperformed in simulating the degradation mechanism of both targets over 1st and zero-order kinetic models. Finally, a photocatalytic degradation mechanism is proposed based on the energy values estimated for the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) using UPS analysis. Graphical abstract: Image 1 Highlights: A facile synthesis method for ZHS/ZTO heterostructure is proposed. Controlled thermal annealing of ZHS affects its compositions and crystallinity. ZHS/ZTO-1 photocatalyst showed 99% and 97% removal of MO and TC, respectively. Scavenging experiments revealed dominating role of OH˙ radicals over superoxide radicals.