A Flame‐Reaction Method for the Large‐Scale Synthesis of High‐Performance SmxCoy Nanomagnets. Issue 41 (4th September 2019)

• Record Type: Journal Article
• Authors: Ma, Zhenhui; Tian, Hui; Cong, Liying; Wu, Qiong; Yue, Ming; Sun, Shouheng
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 41(2019)
• Page Start: 14509
• Page End: 14512
• Publication Date: 2019-09-04
• Subjects: flame reaction -- permanent magnets -- rare-earth-metal magnets; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201907763
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: We report a flame‐reaction method to synthesize high‐performance Sm x Co y ( x =1, y =5; x =2, y =17) particles on a multigram scale. This flame reaction allows the controlled decomposition of Sm(NO3 )3 and Co(NO3 )2 to 320 nm SmCo‐O (SmCoO3 + Co3 O4 ) particles. A 5.8 g sample of SmCo3.8 ‐O particles was coated with CaO and then reduced at 900 °C by Ca to give 4.2 g of 260 nm SmCo5 particles. The SmCo5 particles are strongly ferromagnetic and the aligned particles in epoxy resin exhibit a large room‐temperature coercivity (Hc ) of 41.8 kOe and giant (BH)max (maximum magnetic energy product) of 19.6 MGOe, the highest value ever reported for SmCo5 made by chemical methods. This synthesis can be extended to synthesize Sm2 Co17 particles, providing a general approach to scaling up the synthesis of high‐performance Smx Coy nanomagnets for permanent magnet applications. Abstract : Playing with fire : A flame reaction is used to prepare SmCo–oxide particles that are further reduced to form strongly ferromagnetic Smx Coy particles. The 260 nm SmCo5 particles can be embedded in epoxy resin and aligned to show a large room‐temperature coercivity (Hc =41.8 kOe) and high magnetic energy product (19.6 MGOe).