Experimental and kinetic study on JP-10/air autoignition and the effect of NO2 at high temperatures. (1st February 2023)

• Record Type: Journal Article
• Authors: Shi, Lei; Xu, Ping; Wang, Rui; Tang, Weixin; Ding, Tao; Jiang, Rongpei; Zhang, Changhua
• Is Part Of: Fuel. Volume 333(2023)Part 2
• Publication Date: 2023-02-01
• Subjects: JP-10 -- NO2 effect -- Ignition delay time -- Shock tube -- Kinetic mechanism; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2022.126418
• Languages: English
• ISSNs: 0016-2361

Abstract

Highlights: Ignition delay times of JP-10 and JP-10 with NO2 vitiation in air were measured. NO2 promotes JP-10 ignition at 10 atm but inhibits at 2 atm. A JP-10/NO2 mechanism was developed and well validated by experiments. NO2 can react with JP-10 to affect the consumption of JP-10 fuel during ignition. Abstract: Ignition delay times of JP-10 in air and the vitiation effect of NO2 on JP-10 autoignition at high temperatures were investigated behind reflected shock waves. The experiments were carried out at pressures of 2 and 10 atm, temperatures between 900 and 1460 K, fuel lean and stoichiometric conditions with and without 1.0 % NO2 . The experimental results show that the ignition delay times of JP-10/air decrease with the increase of pressure or the decrease of equivalence ratio. The effect of adding 1.0 % NO2 is pressure dependence. At 10 atm, the addition of NO2 promotes the ignition of fuel, which shortens the ignition delay time. At 2 atm, the addition of 1.0 % NO2 inhibits the ignition of JP-10, which prolongs the ignition delay time. A chemical kinetic mechanism of JP-10/NO2 consisting of 290 species and 1768 reactions was developed by extending from a C0-C5 alkane and a cyclopentene sub-mechanism. The proposed mechanism has been well validated by ignition delay times, laminar flame speeds and species concentration profiles from literature. To further investigate the autoignition of JP-10 and the vitiation effect of NO2, kinetics analyses including reaction pathways and sensitivity coefficients were performed by the developed mechanism. The main consumption pathways of JP-10 in air are H-abstraction reactions from JP-10 by HO2 radicals. With 1.0 % NO2 vitiation, the addition of NO2 has a strong effect on JP-10 consumption via the H-abstraction pathway JP-10 + NO2 = C10 H15 + HONO, which further affects the autoignition of JP-10.