Asymmetric side-chain substitution enables a 3D network acceptor with hydrogen bond assisted crystal packing and enhanced electronic coupling for efficient organic solar cells. Issue 11 (22nd September 2022)

• Record Type: Journal Article
• Authors: Luo, Zhenghui; Gao, Yuan; Lai, Hanjian; Li, Yuxiang; Wu, Ziang; Chen, Zhanxiang; Sun, Rui; Ren, Jiaqi; Zhang, Cai'e; He, Feng; Woo, HanYoung; Min, Jie; Yang, Chuluo
• Is Part Of: Energy & environmental science. Volume 15:Issue 11(2022)
• Page Start: 4601
• Page End: 4611
• Publication Date: 2022-09-22
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/d2ee01848a
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : An asymmetric acceptor BTP-PhC6-C11 shows hydrogen bond assisted and tighter crystal packing and enhanced electronic coupling as compared with symmetric Y6 and BTP-PhC6, and organic solar cells based on PM1:BTP-PhC6-C11 realized a highest PCE of 18.33%. Abstract : Side chain modification on small-molecule acceptors (SMAs) is an effective method to realize high device efficiencies for organic solar cells (OSCs), among which the asymmetric side-chain strategy is a promising one. However, the underlying mechanism of this tactic has not been clearly understood from the aspect of material's eigen-properties, especially the single crystal structure. In this work, for the first time this gap is filled by focusing on parent molecules Y6 and BTP-PhC6, together with the corresponding asymmetric molecule BTP-PhC6-C11 (originally synthesized here). These three acceptors present similar optical and electrochemical properties. The crystallographic analysis and theoretical calculation results demonstrate that asymmetric BTP-PhC6-C11 shows stronger π⋯π interactions between two terminal accepting units, larger electronic couplings in 3D charge transport networks due to the synergistic effect of hydrogen bonding interactions and small steric hindrance, and comparable internal reorganization energies as compared with symmetric Y6 and BTP-PhC6 . Upon pairing these SMAs with polymer donor PM1, the BTP-PhC6-C11 -based device realizes a highest PCE of 18.33% as compared with the devices based on Y6 (17.06%) and BTP-PhC6 (17.43%). The best PCE achieved for the PM1:BTP-PhC6-C11 device is mainly attributed to the larger and more symmetric charge mobility, longer carrier lifetime, enhanced molecular packing along the conjugated backbones of BTP-PhC6-C11, and more suitable phase separation. Overall, our systematic study reveals that asymmetric side-chain substitution is a simple and feasible method to enhance π–π stacking, increase electronic couplings, and thereby promote photovoltaic efficiency.