Fabrication of Discontinuous Dendritic CH3NH3PbBr3 Perovskite Microdisk Arrays for Microlasers. Issue 22 (6th September 2022)

• Record Type: Journal Article
• Authors: Guo, Junhan; Tang, Yang; Li, Longtao; Liu, Bin; Li, Ling; Meng, Fanwen; Qin, Liang; Deng, Zhenbo; Cui, Qiuhong; Lou, Zhidong; Hu, Yufeng; Teng, Feng; Hou, Yanbing
• Is Part Of: Advanced optical materials. Volume 10:Issue 22(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-09-06
• Subjects: methylammonium lead halide perovskites -- microdisk arrays -- whispering gallery mode lasers; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.202201519
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract: Methylammonium (CH3 NH2, MA) lead halide single crystals have attracted attention due to their excellent properties, such as tunable bandgap, high absorption efficiency, long carrier diffusion length, low non‐radiative recombination rate, high gain efficiency, and ultra‐low trap state density. However, excellent methylammonium lead bromine (MAPbBr3 ) microdisk laser arrays reported at present mainly rely on nanoimprint or inkjet printing technology, which highly depends on the equipment. Herein, an approach to prepare high‐quality MAPbBr3 microdisk arrays is developed in which well‐aligned microdisk arrays grow via partial dissolution and recrystallization of dendrites induced by Marangoni flow in a solution self‐assembly growth process. On the same dendrite, the growth direction of the microdisk crystals is highly consistent, and the crystal size distribution is uniform. Besides, the MAPbBr3 microdisks show excellent laser performance with a low threshold of 43.3 µJ cm −2 and a high Q factor ( Q = 2072). The small volume and high‐quality square MAPbBr3 perovskite microdisks have great potential in the application of integrated photoelectric lasers. Abstract : An approach to prepare high‐quality methylammonium lead bromine (MAPbBr3 ) microdisk arrays is developed in which well‐aligned microdisk arrays grow via partial dissolution and recrystallization of dendrites induced by Marangoni flow in a solution self‐assembly growth process. Each microdisk has a regular shape, a smooth edge, extremely low surface roughness, and excellent laser performance.