Manifestation of Strongly Correlated Electrons in a 2D Kagome Metal–Organic Framework. (12th September 2021)

• Record Type: Journal Article
• Authors: Kumar, Dhaneesh; Hellerstedt, Jack; Field, Bernard; Lowe, Benjamin; Yin, Yuefeng; Medhekar, Nikhil V.; Schiffrin, Agustin
• Is Part Of: Advanced functional materials. Volume 31:Number 48(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-09-12
• Subjects: 2D organic nanomaterials -- correlated electron materials -- kondo effect -- metal–organic frameworks -- non‐contact atomic force microscopy -- on‐surface self‐assembly -- scanning tunneling microscopy; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202106474
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: 2D and layered electronic materials characterized by a kagome lattice, whose valence band structure includes two Dirac bands and one flat band, can host a wide range of tunable topological and strongly correlated electronic phases. While strong electron correlations have been observed in inorganic kagome crystals, they remain elusive in organic systems, which benefit from versatile synthesis protocols via molecular self‐assembly and metal‐ligand coordination. Here, direct experimental evidence of local magnetic moments resulting from strong electron–electron Coulomb interactions in a 2D metal–organic framework (MOF) is reported. The latter consists of di‐cyano‐anthracene (DCA) molecules arranged in a kagome structure via coordination with copper (Cu) atoms on a silver surface [Ag(111)]. Temperature‐dependent scanning tunneling spectroscopy reveals magnetic moments spatially confined to DCA and Cu sites of the MOF, and Kondo screened by the Ag(111) conduction electrons. By density functional theory and mean‐field Hubbard modeling, it is shown that these magnetic moments are the direct consequence of strong Coulomb interactions between electrons within the kagome MOF. The findings pave the way for nanoelectronics and spintronics technologies based on controllable correlated electron phases in 2D organic materials. Abstract : Materials with a 2D kagome crystal structure yield potential for a wide range of tunable topological and correlated electron phases. The emergence of local magnetic moments resulting from strong electron‐electron Coulomb interactions in a 2D kagome metal–organic framework is demonstrated. These findings pave the way for tunable electron correlations—and hence controllable electronic and magnetic quantum phases—in 2D organic materials.