Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence. (27th November 2019)

• Record Type: Journal Article
• Authors: Wang, He; Shi, Huifang; Ye, Wenpeng; Yao, Xiaokang; Wang, Qian; Dong, Chaomin; Jia, Wenyong; Ma, Huili; Cai, Suzhi; Huang, Kaiwei; Fu, Lishun; Zhang, Yanyun; Zhi, Jiahuan; Gu, Long; Zhao, Yanli; An, Zhongfu; Huang, Wei
• Is Part Of: Angewandte Chemie. Volume 131:Number 52(2019)
• Page Start: 18952
• Page End: 18958
• Publication Date: 2019-11-27
• Subjects: Festkörperstrukturen -- Ionische Bindung -- Mehrfarbige Emission -- Phosphoreszenz -- π-Wechselwirkungen; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201911331
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Amorphous purely organic phosphorescence materials with long‐lived and color‐tunable emission are rare. Herein, we report a concise chemical ionization strategy to endow conventional poly(4‐vinylpyridine) (PVP) derivatives with ultralong organic phosphorescence (UOP) under ambient conditions. After the ionization of 1, 4‐butanesultone, the resulting PVP‐S phosphor showed a UOP lifetime of 578.36 ms, which is 525 times longer than that of PVP polymer itself. Remarkably, multicolor UOP emission ranging from blue to red was observed with variation of the excitation wavelength, which has rarely been reported for organic luminescent materials. This finding not only provides a guideline for developing amorphous polymers with UOP properties, but also extends the scope of room‐temperature phosphorescence (RTP) materials for practical applications in photoelectric fields. Abstract : Alle Farben des Regenbogens : Ultralange organische Phosphoreszenz (UOP) wurde in einer Serie amorpher Polymere durch Ionisation unter Umgebungsbedingungen ermöglicht. Die UOP‐Emissionsfarbe konnte über den gesamten sichtbaren Bereich (siehe Fotos) durch Variieren der Anregungswellenlänge von Blau nach Rot moduliert werden.