Spontaneous Production of Ultrastable Reactive Oxygen Species on Titanium Oxide Surfaces Modified with Organic Ligands. Issue 17 (8th August 2021) - Ritacco, Ida
Abstract: The spontaneous formation and long‐term surface stabilization of superoxide radicals are observed on specific TiO2 hybrid materials in which titanium is coordinated to an organic ligand. Here the rationale for this uncommon phenomenon is investigated by a synergistic theoretical and experimental approach involving density functional theory (DFT) calculations and spectroscopic techniques. Stoichiometric and reduced anatase (101) surfaces modified with acetylacetone, dibenzoylmethane, and catechol are comparatively examined. These results reveal that the interaction between organic ligands and adsorbed O2 molecules improves when O vacancies are present on the external layer of the surface, promoting O2 reduction. The electronic features of the ligand play a pivotal role for both an effective electronic interaction with the surface and the stabilization of the generated reactive oxygen species. These results agree with experimental data showing that sol–gel‐derived Ti‐diketonate hybrid oxides spontaneously produce very persistent superoxide radicals under ambient conditions, thus holding a high intrinsic oxidative activity. Abstract : The reasons for the spontaneous formation of reactive oxygen species on specific O‐defective TiO2 hybrid materials and the impressive surface stabilization of these species are revealed by density functional theory (DFT) calculations. According with spectroscopic data, the presence of Ti‐acetylacetonate and Ti‐dibenzoylmethanate complexes, unlike the Ti‐catecholate ones, stabilizes the superoxide ion radicals.