An Analytical Framework for the Steady State Impact of Carbonate Compensation on Atmospheric CO2. Issue 4 (26th April 2018)

• Record Type: Journal Article
• Authors: Omta, Anne Willem; Ferrari, Raffaele; McGee, David
• Is Part Of: Global biogeochemical cycles. Volume 32:Issue 4(2018:Apr.)
• Page Start: 720
• Page End: 735
• Publication Date: 2018-04-26
• Subjects: glacial‐interglacial -- carbon cycle -- ocean temperature -- carbonate compensation; Biogeochemical cycles -- Periodicals; Electronic journals; 577.1405
• DOI: 10.1002/2017GB005809
• Languages: English
• ISSNs: 0886-6236

Abstract

Abstract : The deep‐ocean carbonate ion concentration impacts the fraction of the marine calcium carbonate production that is buried in sediments. This gives rise to the carbonate compensation feedback, which is thought to restore the deep‐ocean carbonate ion concentration on multimillennial timescales. We formulate an analytical framework to investigate the impact of carbonate compensation under various changes in the carbon cycle relevant for anthropogenic change and glacial cycles. Using this framework, we show that carbonate compensation amplifies by 15–20% changes in atmospheric CO2 resulting from a redistribution of carbon between the atmosphere and ocean (e.g., due to changes in temperature, salinity, or nutrient utilization). A counterintuitive result emerges when the impact of organic matter burial in the ocean is examined. The organic matter burial first leads to a slight decrease in atmospheric CO2 and an increase in the deep‐ocean carbonate ion concentration. Subsequently, enhanced calcium carbonate burial leads to outgassing of carbon from the ocean to the atmosphere, which is quantified by our framework. Results from simulations with a multibox model including the minor acids and bases important for the ocean‐atmosphere exchange of carbon are consistent with our analytical predictions. We discuss the potential role of carbonate compensation in glacial‐interglacial cycles as an example of how our theoretical framework may be applied. Key Points: We formulate an analytical model for the ocean carbon cycle on multimillennial timescales Carbonate compensation amplifies by 15% changes in atmospheric CO2 due to changes in ocean temperature, salinity, or nutrient utilization Organic matter burial in the ocean, in combination with carbonate compensation, leads to outgassing of CO2 from the ocean to the atmosphere