Crystal structure, electric and microwave dielectric properties of La2Mg(Mg1/3Sb2/3)O6 novel double-perovskite with non-stoichiometric 1:1 cationic ordering. Issue 3 (March 2023)

• Record Type: Journal Article
• Authors: Yang, Li; Yang, Xiaoyan; Fang, Weishuang; Deng, Sihao; He, Lunhua; Liu, Laijun; Fernández-Carrión, Alberto J.; Kuang, Xiaojun
• Is Part Of: Journal of the European Ceramic Society. Volume 43:Issue 3(2023)
• Page Start: 1000
• Page End: 1008
• Publication Date: 2023-03
• Subjects: Complex double perovskite -- Neutron powder diffraction -- Dielectric properties -- Cation ordering; Ceramic materials -- Periodicals; Composite materials -- Periodicals; Matériaux céramiques -- Périodiques; Composites -- Périodiques; Ceramic materials; Composite materials; Periodicals; Electronic journals; 666.05
• DOI: 10.1016/j.jeurceramsoc.2022.10.033
• Languages: English
• ISSNs: 0955-2219

Abstract

Abstract: In this contribution, the novel double-perovskite La2 Mg(Mg1/3 Sb2/3 )O6 has been successfully prepared by solid-state reaction method, and its structure has been determined for the first time by a combination of X-ray and neutron powder diffraction data analysis. The novel material exhibits a thermal expansion of ∼9.1 ppm/°C and a large optical band gap (4.23 eV). The complex impedance data analysis indicates that La2 Mg(Mg1/3 Sb2/3 )O6 features a Debye-like behaviour, with a bulk conductivity, σb, varying between 10 -7 -10 -4 S ‧cm -1 within 500–900 °C temperature range, and activation energy (Ea ) of ∼ 1.36 eV. In addition, the microwave dielectric properties of La2 Mg(Mg1/3 Sb2/3 )O6 sintered at 1625 °C display optimized quality factor (Q× f ) of ∼ 28, 700 GHz ( f = 9.65 GHz), a dielectric constant (εr ) of ∼ 20.2 and temperature coefficient of the resonant frequency ( τ f ) of ∼ − 89 ppm/°C. This work widen the reduced number of A 3 + B 2 / 3 2 + B 1 / 3 5 + O 3 compounds explored so far. Graphical Abstract: ga1