Ionic Liquid Lignosulfonate: Dispersant and Binder for Preparation of Biocomposite Materials. Issue 37 (25th July 2019)

• Record Type: Journal Article
• Authors: Guterman, Ryan; Molinari, Valerio; Josef, Elinor
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 37(2019)
• Page Start: 13044
• Page End: 13050
• Publication Date: 2019-07-25
• Subjects: biomass -- ionic liquids -- lignin -- materials science -- polymers; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201907385
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Ionic liquid lignins are prepared from sodium lignosulfonate by a cation exchange reaction and display glass transition temperatures as low as −13 °C. Diethyleneglycol‐functionalized protic cations inhibit lignin aggregation to produce a free‐flowing "ionic liquid lignin", despite it being a high‐molecular‐weight polyelectrolyte. Through this approach, the properties of both lignin and ionic liquids are combined to create a dispersant and binder for cellulose+gluten mixtures to produce small microphases. Biocomposite testing pieces are produced by hot‐pressing this mixture, yielding a material with fewer defects and improved toughness in comparison to other lignins. The use of unmodified lignosulfonate, acetylated lignosulfonate, or free ionic liquid for similar materials production yields poorer substances because of their inability to maximize interfacial contact and complexation with cellulose and proteins. Abstract : Hot off the press : Lignosulfonate is functionalized to create an ionic liquid with a glass transition temperature ( T g ) of −13 °C. After mixing with cellulose+gluten and hot‐pressing, composite materials are produced and have fewer defects and improved toughness in comparison to other lignins.