Synthesis and performance of a novel polycarboxylate superplasticizer through grafting the β‐cyclodextrin on the side chain by click reaction. Issue 3 (13th August 2021)

• Record Type: Journal Article
• Authors: Li, Bin; Gao, Ruijun; Wang, Ling
• Is Part Of: Journal of applied polymer science. Volume 139:Issue 3(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-08-13
• Subjects: β‐cyclodextrin -- click reaction -- polycarboxylate superplasticizer -- steric hindrance effect; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.51524
• Languages: English
• ISSNs: 0021-8995

Abstract

Abstract: A novel monovinyl β‐cyclodextrin monomer (β‐P) is employed to synthesize polycarboxylate superplasticizers with β‐cyclodextrin (β‐CD) grafted on the end of side chain [PAA‐g‐(β‐P) n HPEG, n is the mass ratio of β‐P in macromonomer, n = 3% ~ 9%]. β‐P is synthesized through grafting β‐CD on the polyoxyethylene (PEO) via click reaction, which is the first try to superimpose the steric hindrance effect of PEO and β‐CD during the preparation of polycarboxylate superplasticizer. FTIR, 1 H NMR, GPC, and DLS are used to characterize the molecular structure of the intermediates and the products. Compared with PAA‐g‐HPEG (PCE0) only with PEO as side chains, cement paste containing PAA‐g‐(β‐P) 7% HPEG has the largest fluidity; PAA‐g‐(β‐P) 9% HPEG corresponds to the best fluidity retention performance; cement paste containing PAA‐g‐(β‐P) n HPEG has shorter setting time. The DLS results reveal that the introduction of β‐CD in PAA‐g‐(β‐P) n HPEG extends the side chain length and increases the steric hindrance effect. The adsorption test results show that the novel PCE has good slump retention performance because it is adsorbed on cement particles less but more lives in the liquid phase with the n increasing. This study provides a new approach to synthesize high‐performance polycarboxylate superplasticizer. Abstract : In this work, a novel method for the preparation of monovinyl β‐CD monomer (β‐P) was designed. Then, β‐P was used as macromonomer and through free radical polymerization a novel polycarboxylate superplasticizer with β‐CD grafted on the side chain was synthesized. This study not only provided a novel approach for preparing monovinyl β‐CD monomer but also developed a new way to design a novel type of polycarboxylate molecule.