Electron-compensation: a valid strategy for chemically stabilizing boron-based clusters with hypercoordinate centres. Issue 94 (7th November 2022)
- Record Type:
- Journal Article
- Title:
- Electron-compensation: a valid strategy for chemically stabilizing boron-based clusters with hypercoordinate centres. Issue 94 (7th November 2022)
- Main Title:
- Electron-compensation: a valid strategy for chemically stabilizing boron-based clusters with hypercoordinate centres
- Authors:
- Jin, Bo
Yuan, Caixia
Lu, Gang
Wu, Yan-Bo - Abstract:
- Abstract : Boron-based clusters with hypercoordinate centres are chemically unstable due to the electron-deficiency of the exposed boron atoms. We propose to chemically stabilize such clusters by electronically compensating the boron atoms via dative π bonds. Abstract : To eliminate the chemical instability caused by the electron-deficiency of boron, two types of usual dative π bonds are recommended for compensating boron atoms in the computational design of boron-based clusters having hypercoordinate centres, which can lead to unusually stable targets for synthesis in the condensed phase.
- Is Part Of:
- Chemical communications. Volume 58:Issue 94(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 94(2022)
- Issue Display:
- Volume 58, Issue 94 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 94
- Issue Sort Value:
- 2022-0058-0094-0000
- Page Start:
- 13095
- Page End:
- 13098
- Publication Date:
- 2022-11-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc05654b ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 24416.xml