Effect of formamidinium (FA) ions on mixed 'A'-site based bromide perovskite (APbBr3) thin films. (9th November 2022)

• Record Type: Journal Article
• Authors: Aloysius, Deepak; Mondal, Arindam; Gupta, Satyajit; Edri, Eran; Mukhopadhyay, Sabyasachi
• Is Part Of: New journal of chemistry. Volume 46:Number 46(2022)
• Page Start: 22229
• Page End: 22236
• Publication Date: 2022-11-09
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d2nj05052h
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Effect of formamidinium (FA) ions on the 'A'-site of a bromide perovskite (APbBr3 ). Abstract : Hybrid organic–inorganic perovskites (HOIPs) have become promising candidates for future photovoltaics (PV) with significant advancements in their performance over recent years. Along with PV, HOIPs possess applications in photodiodes, photodetectors, photocatalysis, and memory devices. Generally, perovskites are structurally flexible to accommodate various cations on their respective sites through compositional engineering, thereby altering the characteristic material properties of the system. HOIPs have ABX3 structures, in which organic or inorganic moieties occupy the monovalent 'A' site. In this work, the effect of formamidinium (FA) on the optical and morphological properties of HOIPs using two different bromide perovskites – FA0.5 MA0.4 Cs0.1 PbBr3 and MA0.9 Cs0.1 PbBr3 – is examined. After 'FA' modification, we noticed a reduction in the bandgap and an increase in the grain size of the FA0.5 MA0.4 Cs0.1 PbBr3 perovskite compared with the MA0.9 Cs0.1 PbBr3 perovskite. As a result, a better photocurrent response during photoelectrochemical analysis and an improved power conversion efficiency (PCE) for photovoltaic devices were detected with the FA-modified HOIP (FA0.5 MA0.4 Cs0.1 PbBr3 ).