Enantioselective Gel Phase Synthesis of Metal–Organic Materials. (11th October 2021)

• Record Type: Journal Article
• Authors: Ghosh, Dipankar; Górecki, Marcin; Pescitelli, Gennaro; Damodaran, Krishna K.
• Is Part Of: Angewandte Chemie. Volume 133:Number 46(2021)
• Page Start: 24611
• Page End: 24615
• Publication Date: 2021-10-11
• Subjects: chiral induction -- enantioselective synthesis -- metal-organic materials -- solid-state CD -- supramolecular gel phase synthesis; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202107040
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: We report the asymmetric synthesis of homochiral metal–organic materials (MOMs) in chiral gels from achiral components. The enantioselectivity of MOMs depends on the chirality of the gel, whereas the synthesis performed in solution phase and achiral gels resulted in conglomerates. Abstract : Asymmetric synthesis of MOMs in gels: Gel phase synthesis of metal–organic materials (MOMs) resulted in homochiral MOMs, which were characterized by single crystal X‐ray diffraction. The chirality of the gelator dictated the handedness of the MOMs and the enantioselectivity was confirmed by solid‐state circular dichroism experiments.