Removal of Phenol from Sour Water by Poly(vinyl Alcohol)/Polyamide‐Reverse Osmosis Membranes. Issue 12 (20th October 2022)

• Record Type: Journal Article
• Authors: Shalaby, Marwa S.; Mansour, Moustapha S.; Eldin, Ahmed Badr; Abdallah, Heba; Ibrahim, Ibrahim Ismail; Abdel Fattah, Marwa; Sołowski, Gaweł
• Is Part Of: Chemical engineering & technology. Volume 45:Issue 12(2022)
• Page Start: 2130
• Page End: 2138
• Publication Date: 2022-10-20
• Subjects: Phenol removal -- Polyamide membranes durability -- Polymeric membranes -- Poly(vinyl alcohol) coating -- Sour water treatment; Chemical engineering -- Periodicals; Chemical processes -- Periodicals; 660.05
• DOI: 10.1002/ceat.202200065
• Languages: English
• ISSNs: 0930-7516

Abstract

Abstract: A commercial thin‐film membrane (unmodified) of polyamide improved by poly(vinyl alcohol) (PVA)‐coated membranes (modified) was investigated for separating phenol in sour water by reverse osmosis. Dependences of pressure and pore surface area on flux and phenol rejection were tested. A graphical correlation was found between the relative flux decline and phenol concentration decrease in the feed. The modified membrane provided rejection of 86 % at 2 bar with the highest permeate flux of 8.46 L m −2 h −1 . The average contact angle for the former membrane was 58.4°, while that for the modified membrane was 49.1°. The reduction in contact angle enhances the surface hydrophilicity of the membrane leading to the antifouling effect. The modified membrane provides 95.4 % flux recovery compared to the unmodified membrane that provides only 66.2 %. Abstract : The relationship between the separation efficiency of phenol from a membrane surface and the filtration efficiency of modified membranes compared to unmodified ones at different operating pressures was evaluated. Synthetic phenol solutions served as model solutions. The physicochemical properties of the modified and unmodified membranes were characterized in terms of hydrophilicity and roughness.